A Study of the Physico-Chemical Features of the {[}(Perfluoroalkyl)methyl]oxirane Amino Derivatives Based on the Hexafluoropropylene Oxide Trimer / Bazhin D. N.,Gorbunova T. I.,Zapevalov A. Ya,Beketov I. V.,Saloutin V. I. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2011. - V. 81, l. 9. - P. 1829-1833.

ISSN/EISSN:

1070-3632 / 1608-3350

Type:

Article

Abstract:

The 1,2-epoxy-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethy l)-5,8-dioxaundecane was synthesized for the first time on the basis of the hexafluoropropylene oxide trimer. We showed that it reacted with diethylamine, morpholine, or N-methylpiperazine to afford the product of regioselective cleavage of the oxirane ring. The processing of nano-sized copper powder with a solution of the obtained hydroxyamine solution in acetone allowed the formation of the hydrophobic metal coating.

Author keywords:

HIGHLY SELECTIVE SYNTHESIS; FLUORINATED EPOXIDES; MONOMERS; IODOPERFLUOROALKANES; POLYMERIZATION; NANOPARTICLES; IODIDES; COPPER

DOI:

10.1134/S1070363211090155

Web of Science ID:

ISI:000297737000015

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3350
Keywords-Plus	HIGHLY SELECTIVE SYNTHESIS; FLUORINATED EPOXIDES; MONOMERS; IODOPERFLUOROALKANES; POLYMERIZATION; NANOPARTICLES; IODIDES; COPPER
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	bazhin@ios.uran.ru
ResearcherID-Numbers	Beketov, Igor/I-3538-2014 Bazhin, Denis/P-4667-2014 Bazhin, Denis/G-1933-2011
ORCID-Numbers	Bazhin, Denis/0000-0003-3972-6995
Number-of-Cited-References	39
Usage-Count-Since-2013	7
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	857RS