Synthesis and Structure of Reaction Products Obtained from 1,2-Epoxyperfluorobutane and Bifunctional Nucleophilic Reagents / Filyakova T. I.,Kodess M. I.,Slepukhin P. A.,Zapevalov A. Ya. // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2009. - V. 45, l. 11. - P. 1700-1706.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

1,2-Epoxyperfluorobutane readily reacts with bifunctional nucleophilic reagents to provide heterocyclic compounds with a pentafluoroethyl substituent. The reaction of this epoxide with thiourea and acetone thiosemicarbazone gave rise to 2-amino-5-pentafluoroethyl-5-fluoro-4(5H)-thiazolinone and 2-iso-propylidenehydrazono-5-pentafluoroethyl-5-fluoro-4-thiazolidinone respectively. The reaction of 1,2-epoxyperfluorobutane with o-phenylenediamine and 2,3-diaminonaphthalene afforded in high yields 3-pentafluoroethyl-2(1H)-quinoxalinone and 3-(pentafluoroethyl)benzo{[}g]-2(1H)-quinoxalinone. The molecular and crystal structure of the obtained fluorine-containing heterocycles was established by XRD analysis.

Author keywords:

нет данных

DOI:

10.1134/S1070428009110219

Web of Science ID:

ISI:000273633900021

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	NOV
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	fc403@ios.uran.ru
Number-of-Cited-References	17
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	5
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	544DY