Perfluoroepoxyoxolanes in the synthesis of fluorine-containing heterocycles / Filyakova T. I.,Zapevalov A. Ya.,Kodess M. I.,Slepukhin P. A.,Saloutin V. I. // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2009. - V. 45, l. 6. - P. 884-889.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

Perfluoro-3,4-epoxyoxolane and 3,4-epoxy-2-trifluoromethylpentafluorooxolane readily reacted with difunctional nucleophiles via opening of the oxirane ring and subsequent heterocyclization. Their reactions with thiourea and o-phenylenediamine gave new fluorine-containing fused heterocyclic compounds, 2-amino-3a-hydroxy-4,4,6,6,6a-pentafluoro-3a,4,6,6a-tetrahydrofuro{[}3,4 -d]{[}1,3]thiazole and 1,1,3,3-tetrafluoro- and 1-trifluoromethyl-1,3,3-trifluoro-1,3-dihydrofuro{[}3,4-b]quinoxalines, respectively. The molecular and crystalline structures of the products were determined by X-ray analysis.

Author keywords:

PERFLUORO; EPOXIDES

DOI:

10.1134/S1070428009060141

Web of Science ID:

ISI:000267898400014

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	PERFLUORO; EPOXIDES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	fc403@ios.uran.ru
Number-of-Cited-References	15
Usage-Count-Since-2013	3
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	469KZ