Reactions of {[}2-iodo-3-(perfluoroalkyl)propyl]glycidyl ethers with alcohols under basic conditions / Bazhin D. N.,Gorbunova T. I.,Zapevalov A. Ya.,Saloutin V. I. // RUSSIAN CHEMICAL BULLETIN. - 2008. - V. 57, l. 11. - P. 2324-2327.

ISSN/EISSN:

1066-5285 / 1573-9171

Type:

Article

Abstract:

On treatment with sodium alkoxides in the corresponding alcohols, {[}2-iodo-3-(perfluoroalkyl)propyl]glycidyl ethers are converted into 3-alkoxy-1-{[}3-(perfluoroalkyl)prop-2-enyloxy]-propan-2-ols in 56-78\% yields, while its reaction with 2,2,2-trifluoroethanol and phenol under phase transfer conditions (NaOH, CH2Cl2-H2O, Bu4N+I-, 35-40 A degrees C) gives 3-alkoxy1-{[}2-iodo-3-(perfluoroalkyl)propoxy]propan-2-ols (yields 45-72\%).

Author keywords:

glycidyl ethers; oxiranes; organofluorine compounds; phase transfer catalysis

DOI:

10.1007/s11172-008-0329-8

Web of Science ID:

ISI:000271939100016

Соавторы в МНС:

Другие поля

Поле	Значение
Month	NOV
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
EISSN	1573-9171
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	bazhin@ios.uran.ru
ResearcherID-Numbers	Bazhin, Denis/G-1933-2011 Bazhin, Denis/P-4667-2014
ORCID-Numbers	Bazhin, Denis/0000-0003-3972-6995
Number-of-Cited-References	8
Usage-Count-Since-2013	2
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	521QY