Synthesis and GC-MS Study of Fluorinated Esters Derived from Thrimethylolpropane / Pervova M. G.,Kirichenko V. E.,Gorbunova T. I.,Zapevalov A. Ya.,Saloutin V. I. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2008. - V. 78, l. 9. - P. 1701-1706.

ISSN/EISSN:

1070-3632 / нет данных

Type:

Article

Abstract:

Zol-gel process was used to synthesize equilibrium mixtures of mono-, di-, and trimester derived from trimethylolpropane and perfluorocarboxylic acids. The elution order of the components of the mixtures from a weakly polar HP-5 column was established. The mass spectra of the synthesized compounds were studied. The GC-MS parameters of the products were compared with the respective parameters of their nonfluorinated analogs. The characteristics of the fluorinated esters have features determined by the esterification degree and the nature of the perfluoroalkyl groups, due to which these compounds can be identified in mixtures.

Author keywords:

нет данных

DOI:

10.1134/S1070363208090107

Web of Science ID:

ISI:000260471800010

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	pervova@ios.uran.ru
Funding-Acknowledgement	Ministry for Industry, Energy, and Science of the Sverdlovsk Region {[}RF-26/07]; Russian Foundation for Basic Research {[}07-0397631-r\_ofi]
Funding-Text	The work was financially supported by the Ministry for Industry, Energy, and Science of the Sverdlovsk Region (contract no. RF-26/07) and the Russian Foundation for Basic Research (project no. 07-0397631-r\_ofi).
Number-of-Cited-References	5
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	3
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	366HQ