Reaction of 2,3-epoxyoctafluorobutane with 2-aminobenzenethiol / Saloutina L. V.,Zapevalov A. Ya.,Saloutin V. I.,Kodess M. I.,Kirichenko V. E.,Pervova M. G.,Chupakhin O. N. // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2006. - V. 42, l. 9. - P. 1307-1312.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

The reaction of 2,3-epoxyoctafluorobutane with 2-aminobenzenethiol in N,N-dimethylacetamide gave 3-(2-aminophenylsulfanyl)-1,1,1,3,4,4,4-heptafluorobutane-2,2-diol. In the reaction of the same compounds in dioxane, 2,3-bis(trifluoromethyl)-3,4-dihydro-2H-1,4-benzothiazin-2-ol was formed as a result of primary attack by the amino group in 2-aminobenzenethiol on the epoxy ring. The same product was obtained by treatment with 2-aminobenzenethiol of 2,3-bis(trifluoromethyl)-2H-1,4-benzoxazin-2-ol which was synthesized from 2,3-epoxyoctafluorobutane and 2-aminophenol.

Author keywords:

INTERNAL PERFLUOROOLEFINS; DISULFIDES; OXIDATION; THIOLS

DOI:

10.1134/S1070428006090090

Web of Science ID:

ISI:000241615500009

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	INTERNAL PERFLUOROOLEFINS; DISULFIDES; OXIDATION; THIOLS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	fc403@ios.uran.ru
Number-of-Cited-References	13
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	2
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	099SI