Reaction of polyfluoro-3-chloro(bromo)-1-butenes with sodium hypohalites and properties of epoxides derived therefrom / Zapevalov AY,Filyakova TI,Kodess MI,Saloutin VI // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2003. - V. 39, l. 7. - P. 919-923.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

Epoxidation of 3-chloro(bromo)heptafluoro-1-butenes and 3,4-dichlorohexafluoro-1-butene with aqueous solutions of sodium hypohalites is accompanied by cleavage of the carbon skeleton at the double bond and formation of polyfluorocarboxylic acid sodium salts as by-products. 3-Chloro(bromo)-1,2-epoxyheptafluoro- and 3,4-dichloro-1,2-epoxyhexafluorobutanes were synthesized and subjected to isomerization into carbonyl compounds by the action of cesium fluoride or antimony pentafluoride.

Author keywords:

нет данных

DOI:

10.1023/B:RUJO.0000003178.3341

Web of Science ID:

ISI:000186587000003

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUL
Publisher	MAIK NAUKA/INTERPERIODICA
Address	C/O KLUWER ACADEMIC-PLENUM PUBLISHERS, 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	saloutin@ios.uran.ru
Number-of-Cited-References	11
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	743RH