From oxides of internal perfluoroolefins to fluorocontaining camphor thiazolinylhydrazones / Saloutina LV,Zapevalov AY,Kodess MI,Lyssenko KA,Antipin MY,Saloutin VI,Chupakhin ON // JOURNAL OF FLUORINE CHEMISTRY. - 2003. - V. 120, l. 1. - P. 41-47.

ISSN/EISSN:

0022-1139 / нет данных

Type:

Article

Abstract:

The reaction of oxides of internal trans- and cis-perfluoroolefins with (1S, 4S)- or racemic camphor thiosemicarbazone leads to the formation of trans- and cis-isomers of (IS, 4S)- or racemic camphor 5'-fluoro-4'-hydroxy-4',5'-di(perfluoroalkyl)-1',3'-thiazolinyl-2'-hydra zones, respectively. Unsymmetrical dodecafluoro-2,3-epoxyhexane yields a mixture of regioisomeric hydrazones. The molecular structure of the trans-isomer of (1S, 4S)-camphor 5'-fluoro-4'-hydroxy-4',5'-bis(trifluoromethyl)-1',3'-thiazolinyl-2'-hyd razone has been established by X-ray crystallography. The quite rare example of cocrystallization of two diastereomers of the latter in homochiral crystal (sp. group P2(1)) has been revealed. (C) 2002 Elsevier Science B.V. All rights reserved.

Author keywords:

oxides of internal perfluoroolefins; camphor thiosemicarbazone; fluorocontaining camphor thiazolinylhydrazones PERFLUORINATED ALPHA-OXIDES

DOI:

10.1016/S0022-1139(02)00283-X

Web of Science ID:

ISI:000181227000007

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAR 1
Publisher	ELSEVIER SCIENCE SA
Address	PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Language	English
Article-Number	PII S0022-1139(02)00283-X
Keywords-Plus	PERFLUORINATED ALPHA-OXIDES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Organic
Author-Email	saloutin@ios.uran.ru
ResearcherID-Numbers	Lyssenko, Konstantin/J-9721-2013
ORCID-Numbers	Lyssenko, Konstantin/0000-0002-3500-1287
Number-of-Cited-References	21
Usage-Count-Since-2013	1
Journal-ISO	J. Fluor. Chem.
Doc-Delivery-Number	649UU