Reaction of internal fluoroolefin oxides with camphor thiosemicarbazone / Saloutina LV,Zapevalov AY,Kodess MI,Saloutin VI,Chupakhin ON // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2001. - V. 37, l. 11. - P. 1522-1527.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

Epoxy derivatives of internal fluoroolefins (both cis and traps isomers) react in a stereospecific manner with (1S)- or rac-camphor thiosemicarbazone in a polar aprotic medium to give the corresponding 5-fluoro-4-hydroxy-4,5-bis(polyfluoroalkyl)thiazol-2-ylhydrazones. From unsymmetrical 2,3-epoxydodecafluorohexane a mixture of regioisomeric hydrazones is formed. According to the H-1 and F-19 NMR data, the resulting traps-hydrazones in (CD3)(2)SO and CDCl3 exist as mixtures of diastereoisomers occurring in a dynamic equilibrium.

Author keywords:

нет данных

DOI:

10.1023/A:1013887515644

Web of Science ID:

ISI:000174149200002

Соавторы в МНС:

Другие поля

Поле	Значение
Month	NOV
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	saloutin@ios.uran.ru
Number-of-Cited-References	9
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	526UZ