Synthesis of polyfluoroalkylated 1,4-diazinols and 1,4-oxazinols using polyfluoro-2,3-epoxyalkanes32+13 / Saloutina LV,Zapevalov AY,Kodess MI,Saloutin VI // JOURNAL OF FLUORINE CHEMISTRY. - 1998. - V. 87, l. 1. - P. 49-55.

ISSN/EISSN:

0022-1139 / нет данных

Type:

Article

Abstract:

It has been found that the reactions of polyfluoro-2,3-epoxyalkanes with ethylenediamine and 2-aminoethanol yield 2,3-di(polyfluoroalkyl)- 1,5,6-trihydro-1,4-diazin-2-ols and 2,3-di(polyfluoroalkyl)-5,6-dihydro-1,4-oxazin-2-ols, respectively. In the case of unsymmetrical oxiranes mixtures of regioisomeric heterocyclic compounds have been obtained. These reactions were found to give some by products-N,N'-bis(polyfluoroacyl) ethylenediamines and N-polyfluoroacyl-2-aminoethanols. (C) 1998 Elsevier Science S.A.

Author keywords:

polyfluoro-2,3-epoxyalkanes; ethylenediamine; 2-aminoethanol; polyfluoroalkylated 1,4-diazinols; polyfluoroalkylated 1,4-oxazinols PERFLUORINATED ALPHA-OXIDES; AMMONIUM

DOI:

10.1016/S0022-1139(97)00102-4

Web of Science ID:

ISI:000072306700008

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JAN 2
Publisher	ELSEVIER SCIENCE SA
Address	PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Language	English
Keywords-Plus	PERFLUORINATED ALPHA-OXIDES; AMMONIUM
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Organic
Number-of-Cited-References	13
Usage-Count-Since-2013	2
Journal-ISO	J. Fluor. Chem.
Doc-Delivery-Number	YZ909