REACTIONS OF 2,3-EPOXYPOLYFLUOROALKANES WITH TRIETHYLAMINE / SALOUTINA LV,KODESS MI,ZAPEVALOV AY // RUSSIAN CHEMICAL BULLETIN. - 1994. - V. 43, l. 12. - P. 2057-2061.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The reactions of 2,3-epoxyperfluoro- and 2,3-epoxy-omega-hydropolyfluoroalkanes with excess triethylamine at elevated temperatures yield secondary alcohols, which are the reduction products of intermediate isomeric ketones. Ring-opening occurs preferentially from the side of the less bulky trifluoromethyl group in all compounds except 2,3-epoxy-6-hydroundecafluorohexane.

Author keywords:

2,3-EPOXYPOLYFLUOROALKANES; TRIETHYLAMINE; POLYFLUORINATED KETONES AND SECONDARY ALPHA-MONOHYDROALCOHOLS

DOI:

10.1007/BF00700169

Web of Science ID:

ISI:A1994QX86900019

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	DEC
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Number-of-Cited-References	15
Usage-Count-Since-2013	1
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	QX869