Synthesis and Evaluation of Lipophilic BTBP Ligands for An/Ln Separation in Nuclear Waste Treatment: The Effect of Alkyl Substitution on Extraction Properties and Implications for Ligand Design (Eur. J. Org. Chem. 8/2012) / Lewis Frank W.,Harwood Laurence M.,Krasnov Victor P. // EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - 2012. - V. , l. 8.

ISSN/EISSN:

1434-193X / нет данных

Type:

Article

Abstract:

The cover picture shows four radiochemical gloveboxes used for working with plutonium and other a-active radioactive materials as the background image. The gloveboxes contain centrifugal contactors and mixer-settler rigs for use in laboratory-scale solvent extraction, actinide oxide dissolution and aqueous actinide chemistry and spectroscopy. The picture is courtesy of Dr. Robin Taylor, National Nuclear Laboratory, Sellafield, Seascale, Cumbria CA20 1PG, UK. The foreground represents the selective extraction of AmIII over EuIII by new 6,6'-bis(triazinyl)-2,2'-bipyridine (BTBP) ligands, a family of ligands currently under study for the separation of actinides from lanthanides in a proposed future selective actinide extraction (SANEX) process. This separation is foreseen as an important step in reducing the long-term radiotoxicity of nuclear waste. Details are discussed in the article by F. W. Lewis, L. M. Harwood et al. on p. 1509 ff.

Author keywords:

нет данных

DOI:

10.1002/ejoc.201290015

Web of Science ID:

ISI:000300930800001

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	MAR
Publisher	WILEY-V C H VERLAG GMBH
Address	PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Usage-Count-Since-2013	26
Journal-ISO	Eur. J. Org. Chem.
Doc-Delivery-Number	900ZI