Nonenzymatic Acylative Kinetic Resolution of Racemic Amines and Related Compounds / Krasnov Victor P.,Gruzdev Dmitry A.,Levit Galina L. // EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - 2012. - V. , l. 8. - P. 1471-1493.

ISSN/EISSN:

1434-193X / 1099-0690

Type:

Review

Abstract:

Acylative kinetic resolution of racemic amines occupies a highly important place among the methods for preparation of enantio enriched or pure amines. Nonenzymatic acylative kinetic resolution is usually carried out in the presence of chiral acyl-transfer catalysts or under the action of chiral enantio- or diastereoselective resolving agents. Recently, this line of investigations has been rapidly developed and very interesting results of design and synthetic application of both new catalysts and chiral acylating agents have been obtained. This microreview summarizes the recent advances in this area.

Author keywords:

Kinetic resolution; Acylation; Amines; Amides ENANTIOSELECTIVE ACYL TRANSFER; OPTICALLY-ACTIVE DIAZIRIDINES; PLANAR-CHIRAL DERIVATIVES; N-HETEROCYCLIC CARBENES; SECONDARY ALKYL AMINES; BETA-HYDROXY AMINES; ASYMMETRIC-SYNTHESIS; ENANTIOMERIC EXCESS; ABSOLUTE-CONFIGURATION; NUCLEOPHILIC CATALYSIS

DOI:

10.1002/ejoc.201101489

Web of Science ID:

ISI:000300930800004

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	MAR
Publisher	WILEY-V C H VERLAG GMBH
Address	POSTFACH 101161, 69451 WEINHEIM, GERMANY
Language	English
EISSN	1099-0690
Keywords-Plus	ENANTIOSELECTIVE ACYL TRANSFER; OPTICALLY-ACTIVE DIAZIRIDINES; PLANAR-CHIRAL DERIVATIVES; N-HETEROCYCLIC CARBENES; SECONDARY ALKYL AMINES; BETA-HYDROXY AMINES; ASYMMETRIC-SYNTHESIS; ENANTIOMERIC EXCESS; ABSOLUTE-CONFIGURATION; NUCLEOPHILIC CATALYSIS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	ca@ios.uran.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}10-03-00084]; State Program for Supporting of Leading Scientific Schools of the Russian Federation {[}65261.2010.3]
Funding-Text	The work was financially supported by the Russian Foundation for Basic Research (grant number 10-03-00084), the State Program for Supporting of Leading Scientific Schools of the Russian Federation (grant number NSh 65261.2010.3).
Number-of-Cited-References	178
Usage-Count-Last-180-days	3
Usage-Count-Since-2013	67
Journal-ISO	Eur. J. Org. Chem.
Doc-Delivery-Number	900ZI