Nucleophilic substitution of halogen in 4-halo derivatives of glutamic acid .3. High pressure effect on the stereochemical result of the reaction / Krasnov VP,Koroleva MA,Rusinov GL // RUSSIAN CHEMICAL BULLETIN. - 1996. - V. 45, l. 3. - P. 543-544.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

Reactions of diastereomeric dialkyl N-phthaloyl-4-haloglutamates with para-anisidine were studied at high pressure, and an additional confirmation of the exact S(N)2 mechanism of the reactions was obtained. Quantitative parameters of the relative reactivity of the diastereomers were found in various solvents, which made it possible to perform the desired synthesis of products of diastereomeric substitution.

Author keywords:

glutamic acid; diastereoselectivity; nucleophilic substitution; reaction rate constant; high pressure

DOI:

10.1007/BF01435778

Web of Science ID:

ISI:A1996UX57300009

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	MAR
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Number-of-Cited-References	8
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	UX573