NUCLEOPHILIC-SUBSTITUTION OF HALOGEN IN 4-HALOGENATED DERIVATIVES OF GLUTAMIC-ACID .1. SOLVENT EFFECT / KRASNOV VP,KOROLEVA MA // RUSSIAN CHEMICAL BULLETIN. - 1995. - V. 44, l. 4. - P. 631-634.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The reaction of nucleophilic substitution of bromine by p-anisidine in dimethyl (2S,4S)- and (2S,4R)-N-phthaloyl-4-bromoglutamates proceeds according to the S(N)2 mechanism. The relative reactivity of diastereomers in various solvents was studied.

Author keywords:

GLUTAMIC ACID; DIASTEREOSELECTIVITY; NUCLEOPHILIC SUBSTITUTION; RATE CONSTANT; SOLVENT EFFECT

DOI:

10.1007/BF00698492

Web of Science ID:

ISI:A1995RR52700009

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	APR
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Number-of-Cited-References	18
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	RR527