Thermodynamic Modeling of the Reaction of Polychlorinated Biphenyls with Sodium Methoxide / Kulikova T. V.,Maiorova A. V.,Shunyaev K. Yu.,Gorbunova T. I.,Saloutin V. I.,Chupakhin O. N. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2013. - V. 83, l. 5. - P. 893-900.

ISSN/EISSN:

1070-3632 / нет данных

Type:

Article

Abstract:

Thermochemical parameters, like standard enthalpy of formation (Delta H-298(0)), enthalpy increment from 0 to 298 K (H-298(0) - H-0(0)), standard heat capacity (C-p298(0)) and its temperature dependence {[}Co(T)], and entropy (S-298(0)), were calculated for the gaseous methoxy derivatives formed from polychlotinated biphenyl (PCB) congeners. Thermodynamic modeling and the HSC software were used to evaluate the reactivity of PCB congeners toward sodium methoxide in DMSO, and the calculation results were compared with experimental data.

Author keywords:

ALKOXIDES

DOI:

10.1134/S1070363213050034

Web of Science ID:

ISI:000321777900003

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	MAY
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	ALKOXIDES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	kuliko@gmail.com
ResearcherID-Numbers	Kulikova, Tatyana/A-3404-2014 Shunyaev, Konstantin/A-3916-2014
Funding-Acknowledgement	Presidium of the Russian Academy of Sciences {[}12-P-3-1008]; Ural Branch of the Russian Academy of Sciences {[}12-M-34-2036]
Funding-Text	The work was financially supported by a program of the Presidium of the Russian Academy of Sciences (project no. 12-P-3-1008) and Ural Branch of the Russian Academy of Sciences (project no. 12-M-34-2036).
Number-of-Cited-References	17
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	7
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	182XK