Reaction of polychlorinated biphenyls and benzenes with neopentyl glycol / Pervova M. G.,Gorbunova T. I.,Samorukova M. A.,Saloutin V. I.,Chupakhin O. N. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2012. - V. 82, l. 3. - P. 428-435.

ISSN/EISSN:

1070-3632 / нет данных

Type:

Article

Abstract:

The reactions of a mixture of 1,2,3- and 1,2,4-trichlorobenzene and polychlorinated biphenyls congeners of the industrial mixture Sovol with neopentyl glycol in the presence of alkali in DMSO medium was studied. In the conditions of nucleophilic substitution the aromatic compounds are converted completely. Using the method of gas chromatography with flame ionization and mass spectrometric detectors the structure of all synthesized compounds was studied and the following series of increasing reactivity of the polychlorinated biphenyls congeners was revealed: tetra- < penta- < hexachlorobiphenyls. The process can serve as a preliminary step of the preparation of industrial waste for the subsequent biological degradation.

Author keywords:

BIODEGRADATION; PCBS

DOI:

10.1134/S1070363212030115

Web of Science ID:

ISI:000303070100011

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	MAR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	BIODEGRADATION; PCBS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	gorbunova@ios.uran.ru
Funding-Acknowledgement	Ural Branch of Russian Academy of Sciences {[}09-C-3-1016]
Funding-Text	This work was supported by the Ural Branch of Russian Academy of Sciences (project no. 09-C-3-1016).
Number-of-Cited-References	11
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	5
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	929MU