Reactivity features of polychlorobiphenyl congeners in the nucleophilic substitution reactions / Gorbunova T. I.,Pervova M. G.,Saloutin V. I.,Chupakhin O. N. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2012. - V. 82, l. 1. - P. 138-143.

ISSN/EISSN:

1070-3632 / нет данных

Type:

Article

Abstract:

Groups of congeners and individual congeners of polychlorobiphenyls contributing to the composition of the technical mixture ``Sovol{''} (PCB 60, PCB 64, PCB 70, PCB 74, PCB 97, PCB 101, PCB 105, PCB 110, PCB 118, PCB 138, PCB 149, PCB 156, and PCB 163) were synthesized by the reaction of aryl-aryl coupling. The interaction of the congeners with sodium methoxide was performed and their complete conversion was proved. By means of gas chromatography-mass spectrometry the PCBs methoxy derivatives were identified. The data on the reactivity of the individual polychlorobiphenyl congeners were precised.

Author keywords:

POLYCHLORINATED-BIPHENYLS; IRON; DECHLORINATION; NANOPARTICLES; PCBS

DOI:

10.1134/S1070363212010227

Web of Science ID:

ISI:000300454700022

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	JAN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	POLYCHLORINATED-BIPHENYLS; IRON; DECHLORINATION; NANOPARTICLES; PCBS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	gorbunova@ios.uran.ru
Funding-Acknowledgement	Ural Branch of Russian Academy of Sciences {[}09-C-3-1016]; Russian Foundation for Basic Research {[}08-03-99045]
Funding-Text	This work was supported by the Ural Branch of Russian Academy of Sciences (project no. 09-C-3-1016) and the Russian Foundation for Basic Research (project no. 08-03-99045).
Number-of-Cited-References	18
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	11
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	894VF