Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N `-1,2-phenylen-bis(beta-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes / Chizhov Dmitrii L.,Pervova Marina G.,Samorukova Mariya A.,Khmara Ekaterina F.,Filyakova Vera I.,Saloutin Viktor I.,Charushin Valery N. // JOURNAL OF FLUORINE CHEMISTRY. - 2011. - V. 132, l. 6. - P. 394-401.

ISSN/EISSN:

0022-1139 / нет данных

Type:

Article

Abstract:

An effecient synthetic method for fluorinated tridentate beta-aminoenones and tetradentate bis(beta-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(beta-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described. (C) 2011 Elsevier B.V. All rights reserved.

Author keywords:

Amination; Fluorinated ligands; Complexes; Gas-chromatography-mass-spectrometry SCHIFF-BASE LIGANDS; METAL-COMPLEXES; COPPER(II) COMPLEXES; MAGNETIC-RESONANCE; GAS-CHROMATOGRAPHY; NICKEL(II); 1,2-DIAMINOETHANE; ETHYLENEDIAMINE; PRECURSORS; OXIDATION

DOI:

10.1016/j.jfluchem.2011.03.018

Web of Science ID:

ISI:000292440600004

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	ELSEVIER SCIENCE SA
Address	PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Language	English
Keywords-Plus	SCHIFF-BASE LIGANDS; METAL-COMPLEXES; COPPER(II) COMPLEXES; MAGNETIC-RESONANCE; GAS-CHROMATOGRAPHY; NICKEL(II); 1,2-DIAMINOETHANE; ETHYLENEDIAMINE; PRECURSORS; OXIDATION
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Organic
Author-Email	dlchizhov@ios.uran.ru
Funding-Acknowledgement	Ural Division of the RAS {[}09-M-23-2006, 09-P-3-1013]
Funding-Text	The study was supported by the Ural Division of the RAS (programs 09-M-23-2006 and 09-P-3-1013). Spectroscopic investigations and elemental analysis have been made in the Institute of Organic Synthesis, Ural Division of the RAS, Ekaterinburg, Russian Federation.
Number-of-Cited-References	57
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	8
Journal-ISO	J. Fluor. Chem.
Doc-Delivery-Number	788JG