Bis(1,1,1,3,5,5,5-heptafluoro-4-iminopent-2-ene-2-aminato)copper(ii) - a new metal-containing matrix in the design of heterospin systems / Fokin S. V.,Ovcharenko V. I.,Romanenko G. V.,Tretyakov E. V.,Bogomyakov A. S.,Saloutina L. V.,Filyakova T. I.,Saloutin V. I.,Charushin V. N.,Chupakhin O. N. // RUSSIAN CHEMICAL BULLETIN. - 2011. - V. 60, l. 5. - P. 816-823.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The first heterospin compounds based on bis(1,1,1,3,5,5,5-heptafluoro-4-iminopent-2-ene-2-aminato)copper(ii) (CuL(2)) and nitronyl nitroxide radicals, 2-R-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyls (NIT-R, where R = H, Me, Ph, and 1-methylpyrazol-4-yl), were synthesized and structurally characterized. An important peculiarity of the structure of synthesized solid phases is the formation of a supramolecular structure due to hydrogen bonds between the oxygen atoms of the nitronyl nitroxide fragments of NIT-R and the hydrogen atoms of the NH groups of CuL(2).

Author keywords:

copper(II); copper(II) bischelates; nitroxides; X-ray diffraction analysis; magnetic properties NITROXIDES

DOI:

10.1007/s11172-011-0130-y

Web of Science ID:

ISI:000297153800006

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAY
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	NITROXIDES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	Victor.Ovcharenko@tomo.nsc.ru charushin@prm.uran.ru
ResearcherID-Numbers	Tretyakov, Evgeny/A-7163-2014 Fokin, Sergey/A-7051-2014 Bogomyakov, Artem/A-7079-2014
ORCID-Numbers	Tretyakov, Evgeny/0000-0003-1540-7033 Bogomyakov, Artem/0000-0002-6918-5459 Romanenko, Galina/0000-0001-8852-2759
Funding-Acknowledgement	Russian Foundation for Basic Research {[}08-03-00025, 09-03-00091, 09-03-12108]; Division of Inorganic Materials Chemistry of the Russian Academy of Sciences {[}5.7.2]; Ural Branch of the Russian Academy of Sciences {[}09-M-23-2006, 09-P-3-1013, 47]; Siberian Branch of the Russian Academy of Sciences {[}47]
Funding-Text	This work was financially supported by the Russian Foundation for Basic Research (Project Nos 08-03-00025, 09-03-00091, and 09-03-12108), the Division of Inorganic Materials Chemistry of the Russian Academy of Sciences (Program ``Chemistry and Physical Chemistry of Supramolecular Systems and Atomic Clusters,{''} No. 5.7.2), the Ural Branch of the Russian Academy of Sciences (Project Nos 09-M-23-2006 and 09-P-3-1013), and the Joint Project of the Ural Branch and Siberian Branch of the Russian Academy of Sciences (Project No. 47).
Number-of-Cited-References	11
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	2
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	849VQ