Synthesis and crystal structures of the heptafluoroacetylacetonatocopper(ii) and 4-iminoheptafluoropent-2-ene-2-aminatocopper(ii) complexes with triphenylphosphine oxide and pyridine / Filyakova T. I.,Saloutina L. V.,Slepukhin P. A.,Saloutin V. I.,Chupakhin O. N. // RUSSIAN CHEMICAL BULLETIN. - 2009. - V. 58, l. 6. - P. 1132-1138.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

New chelate heptafluoroacetylacetonatocopper(ii) complexes with triphenylphosphine oxide and pyridine as well as the 4-iminoheptafluoropent-2-ene-2-aminatocopper(ii) complex with triphenylphosphine oxide were synthesized. The molecular and crystal structures of the complexes were studied by X-ray diffraction analysis. The reaction of 2-amino-4-imino-heptafluoropent-2-ene with CuO affords bis(4-imino-1,1,1,3,5,5,5-heptafluoropent-2-ene-2-aminato)copper(ii) in similar to 90\% yield.

Author keywords:

heptafluoroacetylacetone; 2-amino-4-iminoheptafluoropent-2-ene; triphenyl-phosphine oxide; pyridine; copper(II) chelate complexes; X-ray diffraction analysis COPPER(II) HEXAFLUOROACETYLACETONATE; METAL

DOI:

10.1007/s11172-009-0147-7

Web of Science ID:

ISI:000277098500006

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	JUN
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	COPPER(II) HEXAFLUOROACETYLACETONATE; METAL
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	saloutin@ios.uran.ru
Funding-Acknowledgement	Council on Grants at the President of the Russian Federation {[}NSh-3758.2008.3]
Funding-Text	This work was financially supported by the Council on Grants at the President of the Russian Federation (Program for State Support for Leading Scientific Schools of the Russian Federation, Grant NSh-3758.2008.3).
Number-of-Cited-References	18
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	3
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	588UB