TRANSESTERIFICATION OF COPPER(II) BETA-KETOESTERATES AND ACYLPYRUVATES WITH BORNEOL / SALOUTIN VI,KONDRATEV PN,SKRYABINA ZE // RUSSIAN CHEMICAL BULLETIN. - 1993. - V. 42, l. 5. - P. 858-860.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

Transesterification of copper(II) acetoacetates, copper(II) trifluoroacetoacetate, and copper(II) acylpyruvates with borneol gives the copper(II) chelates of the corresponding bornyl esters in 92-95 \% yields. Bornyl acetyl- and perfluoroacylpyruvates were synthesized for the first time by decomposing the respective chelates with hydrogen chloride. Bornyl acylpyruvates react with hydrazine hydrate to give 5-alkyl-3-bornyloxycarbonylpyrazoles.

Author keywords:

BETA-KETO ESTERS; ACYLPYRUVATES; COPPER CHELATES; BORNEOL, TRANSESTERIFICATION; HYDRAZINE HYDRATE; 5-ALKYL-3-BORNYLOXYCARBONYLPYRAZOLES ESTERS; ACIDS

DOI:

10.1007/BF00698945

Web of Science ID:

ISI:A1993NJ89900017

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	MAY
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013
Language	English
Keywords-Plus	ESTERS; ACIDS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Number-of-Cited-References	8
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	NJ899