LIQUID-PHASE OXIDATION OF ANTHRACENE BY HYDROGEN-PEROXIDE IN THE PRESENCE OF HETEROGENIZED VANADYL ACETYLACETONATE / MENSHIKOV SY,VURASKO AV,PETROV LA,MOLOCHNIKOV LS,NOVOSELOVA AA,SKRYABINA ZE,SALOUTIN VI // BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. - 1992. - V. 41, l. 4, 1. - P. 619-622.

ISSN/EISSN:

1063-5211 / нет данных

Type:

Article

Abstract:

The synthesis of heterogenized vanadyl acetylacetonate was accomplished by alkylation of a chloromethylated styrene-divinylbenzene copolymer via activation by Co(II) complexes. The effect of heterogenization on the structure of the complexes and their catalytic properties in the peroxide oxidation of anthracene was investigated by kinetic studies and EPR spectroscopy. Increased stability during oxidation of the catalytic centers of the polymer sample as compared with homogeneous vanadyl acetylacetonate was demonstrated.

Author keywords:

ACETYLACETONE; HETEROGENIZED; POLYSTYRENE; VANADYL; ANTHRACENE; OXIDATION

DOI:

10.1007/BF01150880

Web of Science ID:

ISI:A1992KB85500004

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	APR
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Number-of-Cited-References	15
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	8
Doc-Delivery-Number	KB855