Features of the reaction of 3(5)-methyl-5(3)-trifluoromethylpyrazole with chloroform. Synthesis and structure of fluorinated analogs of tris(pyrazol-1-yl)methane / Boltacheva N. S.,Slepukhin P. A.,Pervova M. G.,Samorukova M. A.,Lavrenova L. G.,Filyakova V. I.,Charushin V. N. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2012. - V. 82, l. 8. - P. 1444-1450.

ISSN/EISSN:

1070-3632 / 1608-3350

Type:

Article

Abstract:

Reaction of 3(5)-methyl-5(3)-trifluoromethylpyrazole (I) with chloroform leads to a complex mixture of compounds. The main components are \{bis{[}(5-methyl-3-trifluoromethyl)pyrazol-1-yl](3-methyl-5-trifluorome thyl)pyrazol-1-yl\}methane, bis\{{[}(3-methyl-5-trifluoromethyl)pyrazol-1-yl](5-methyl-3-trifluorome thyl)-pyrazol-1-yl\}methane, and tris{[}(3-methyl-5-trifluoro-methyl)pyrazol-1-yl]methane. The structure of isomeric substances was proved by XRD method.

Author keywords:

TRIS(PYRAZOLYL)METHANE LIGANDS; SPIN-CROSSOVER; COORDINATION; COMPLEXES; CHEMISTRY; IRON(II); METHANE

DOI:

10.1134/S1070363212080191

Web of Science ID:

ISI:000308820000019

Соавторы в МНС:

Другие поля

Поле	Значение
Month	AUG
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3350
Keywords-Plus	TRIS(PYRAZOLYL)METHANE LIGANDS; SPIN-CROSSOVER; COORDINATION; COMPLEXES; CHEMISTRY; IRON(II); METHANE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	vif@ios.uran.ru
Funding-Acknowledgement	program ``State support for leading scientific schools{''} {[}NLS-65261.2010.3]; Federal Target Program ``Research and scientific-pedagogical staff of innovative Russia{''} {[}02.740.11.0628]
Funding-Text	This work was financially supported by the program ``State support for leading scientific schools{''} (Grant no. NLS-65261.2010.3) and the Federal Target Program ``Research and scientific-pedagogical staff of innovative Russia{''} for 2009-2013 (State contract no. 02.740.11.0628).
Number-of-Cited-References	21
Usage-Count-Since-2013	4
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	006LF