Unusual transformations of lithium enolate of ethyl 4,4,4-trifluoro-3-oxobutanoate / Boltacheva N. S.,Slepukhin P. A.,Chizhov D. L.,Yachevskii D. S.,Filyakova V. I.,Charushin V. N. // RUSSIAN CHEMICAL BULLETIN. - 2012. - V. 61, l. 3. - P. 563-567.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The present paper describes unusual reactions of lithium enolate of ethyl 4,4,4-trifluoro-3-oxobutanoate with ammonium acetate and 1-aminonaphthalene. These reactions produce 4-amino-2,6-bis(trifluoromethyl)pyridine and 4-trifluoromethyl-2-{[}(Z)-1,1,1-trifluoroprop-1-en-2-ol-1-yl]benzo{[}h] quinoline, respectively. The reaction of 1,1,7,7,7-hexafluoroheptane-2,4,6-trione hydrate with 1-naphthylamine gives a mixture of 4-trifluoromethyl-2-{[}(Z)-1,1,1-trifluoroprop-1-en-2-ol-1-yl]benzo{[}h] quinoline and N,N'-bis(naphth-1-yl)-2,6-bis(trifluoromethyl)pyridine-4(1H)-imine, respectively.

Author keywords:

lithium enolate of ethyl 4,4,4-trifluoro-3-oxobutanoate; 4-amino-2,6-bis(trifluoromethyl)pyridine; 4-trifluoromethyl-2-{[}(Z)-1,1,1-trifluoroprop-1-en-2-ol-1-yl]benzo{[}h] quinoline; 1,1,7,7,7-hexaflu CONTAINING BETA-DIKETONES; SALTS

DOI:

10.1007/s11172-012-0082-x

Web of Science ID:

ISI:000312494700010

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAR
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	CONTAINING BETA-DIKETONES; SALTS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	vif@ios.uran.ru
Funding-Acknowledgement	Council on Grants from the Russian Federation (Program for State Support of Leading Scientific Schools of the Russian Federation) {[}NSh-65261.2010.3]
Funding-Text	This work was financially supported by the Council on Grants from the President of the Russian Federation (Program for State Support of Leading Scientific Schools of the Russian Federation, Grant NSh-65261.2010.3).
Number-of-Cited-References	23
Usage-Count-Since-2013	7
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	056MQ