Bis(acetylaryl) podands in the synthesis of fluorine-containing bis(beta-diketones) joined by a polyether spacer / Chizhov D. L.,Slepukhin P. A.,Ovchinnikova I. G.,Fedorova O. V.,Rusinov G. L.,Filyakova V. I.,Charushin V. N. // RUSSIAN CHEMICAL BULLETIN. - 2010. - V. 59, l. 11. - P. 2122-2125.

ISSN/EISSN:

1066-5285 / 1573-9171

Type:

Article

Abstract:

O-Alkylation of 2-acetylphenols with alpha,omega-dichloro derivatives of oligoethylene glycols in the presence of KOH and Al2O3 in DMF gave the corresponding podands. Their condensation with ethyl trifluoroacetate afforded fluorine-containing bis(beta-diketones) with the aryl fragments linked by conformationally flexible polyether spacers.

Author keywords:

the Williamson reaction; O-alkylation; phenols; podands; ethyl trifluoroacetate; organofluorine compounds; beta-diketones; nanosized alumina; X-ray diffraction analysis

DOI:

10.1007/s11172-010-0365-z

Web of Science ID:

ISI:000289006200016

Соавторы в МНС:

Другие поля

Поле	Значение
Month	NOV
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
EISSN	1573-9171
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	vif@ios.uran.ru
Funding-Acknowledgement	Council on Grants at the President of the Russian Federation {[}NSh-65261.2010.3]; State Contract {[}02 740 11 0260]; Ural Branch of the Russian Academy of Sciences {[}09-T-3-1024 IRI]
Funding-Text	This work was financially supported by the Council on Grants at the President of the Russian Federation (State Support Program for Leading Scientific Schools, Grant NSh-65261.2010.3), the State Contract 02 740 11 0260, and the Ural Branch of the Russian Academy of Sciences (Program 09-T-3-1024 IRI).
Number-of-Cited-References	14
Usage-Count-Since-2013	2
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	743GR