Fluorinated lithium 1,3-diketonates as reagents to modify podands and crown-ethers / Boltachova Nadezhda S.,Fedorova Olga V.,Ovchinnikova Irina G.,Kazheva Olga N.,Chekhlov Anatoliy N.,Dyachenko Oleg A.,Rusinov Gennady L.,Filyakova Vera I.,Charushin Valeriy N. // JOURNAL OF FLUORINE CHEMISTRY. - 2007. - V. 128, l. 7, SI. - P. 762-768.

ISSN/EISSN:

0022-1139 / нет данных

Type:

Article; Proceedings Paper

Abstract:

Fluorinated enaminoketones, a new type of ligands, bearing two independent coordination centers (polyether's and fluorinated enaminoketones fragments) have been obtained. The crystal structure of the Cu(II) complex of 1,5-bis-{[}2-(4,4',4'-trifluoro-1'-methyl-3-oxo-but-1'-enylamino)-phenox y]-3-oxapentane (10) has been elucidated by X-ray crystallography. The results obtained show that the complex 10 consists of two crystallographically independent molecules C26H24CuF6N2O5 (A and B), and the metal atom in the complex 10 has four-coordinated arrangement, as a polyhedron with a distorted square with two nitrogen and two oxygen atoms located in corners. (c) 2007 Elsevier B.V. All rights reserved.

Author keywords:

fluorine-containing lithium 1,3-diketonates; fluorine-containing enaminoketones; crown-ethers; podands; X-ray crystallography CONTAINING BETA-DIKETONES; DERIVATIVES; SALTS; AMINES

DOI:

10.1016/j.jfluchem.2007.04.017

Web of Science ID:

ISI:000248429900014

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUL
Note	7th All-Russian Conference on Fluorine Chemistry, INEOS, Moscow, RUSSIA, JUN 05-09, 2006
Publisher	ELSEVIER SCIENCE SA
Address	PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Language	English
Keywords-Plus	CONTAINING BETA-DIKETONES; DERIVATIVES; SALTS; AMINES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Organic
Author-Email	vif@ios.uran.ru
Number-of-Cited-References	25
Usage-Count-Since-2013	3
Journal-ISO	J. Fluor. Chem.
Doc-Delivery-Number	195RS