Interaction of fluoroalkyl-containing beta-diketones with amines / Filyakova VI,Ratner VG,Karpenko NS,Pashkevich KI // RUSSIAN CHEMICAL BULLETIN. - 1996. - V. 45, l. 9. - P. 2163-2168.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The composition of products of the interaction of asymmetric fluoroalkyl-containing beta-diketones with amines was studied. Mixtures of regioisomeric beta-aminovinylketones and products of cleavage and secondary condensation are formed, depending on the temperature, the solvent, the nature of the fluorinated and nonfluorinated substituents in the beta-diketone, and the basicity of the amine. The major product is a beta-aminovinylketone in which the NH2 group is removed from the fluoroalkyl substituent. No beta-aminovinylimines, products of condensation involving two electrophilic centers, were observed.

Author keywords:

fluoroalkyl-containing beta-diketones, amines, condensation; regioisomeric beta-aminovinylketones; beta-aminovinylimines

DOI:

10.1007/BF01430731

Web of Science ID:

ISI:A1996WN09100023

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	SEP
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU, 233 SPRING ST, NEW YORK, NY 10013
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Number-of-Cited-References	11
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	WN091