Structure of substituted 2-(phenoxy)benzimidazoles / Pavlova I. S.,Pervova I. G.,Lipunova G. N.,Novikova R. K.,Slepukhin P. A.,Lipunov I. N. // CRYSTALLOGRAPHY REPORTS. - 2013. - V. 58, l. 2. - P. 271-274.

ISSN/EISSN:

1063-7745 / нет данных

Type:

Article

Abstract:

The synthesis and X-ray diffraction study of 1-benzyl-2-{[}2-(5-ethyltetrazole-2-yl)-phenoxy]-1H-benzimidazole and 1-benzyl-2-{[}2-(5-ethyltetrazole-2-yl)-4-nitrophenoxy]-1H-benzimidazole single crystals have been performed. The oxidative splitting of an azo-hydrazone group of 1-(2-hydroxy-(5-nitro)phenyl)-3-ethyl-5-(benzylbenzimidazolyl)formazans, a break in the C2-N1 bond, the interaction of o-hydroxyl group of aryl fragment with oxygen, and the formation of new 2-(phenoxy)benzimidazoles are found to occur in the presence of perchlorate iron(III).

Author keywords:

нет данных

DOI:

10.1134/S106377451302020X

Web of Science ID:

ISI:000316677100014

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	MAR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Crystallography
Web-of-Science-Categories	Crystallography
Author-Email	biosphera@usfeu.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}11-03-90724-mob\_st, 11-03-00181a]
Funding-Text	This study was supported by the Russian Foundation for Basic Research, project nos. 11-03-90724-mob\_st and 11-03-00181a.
Number-of-Cited-References	7
Usage-Count-Since-2013	5
Journal-ISO	Crystallogr. Rep.
Doc-Delivery-Number	113OJ