Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds / Pavlova I. S.,Pervova I. G.,Belov G. P.,Khasbiullin I. I.,Slepukhin P. A. // PETROLEUM CHEMISTRY. - 2013. - V. 53, l. 2. - P. 127-133.

ISSN/EISSN:
0965-5441 / нет данных
Type:
Article
Abstract:
A number of iron(II) complexes have been synthesized on the basis of benzothiazolylformazans, and their structure and composition have been characterized by elemental analysis, mass spectrometry, and X-ray analysis. The catalytic behavior of Fe(II) formazanates in the reaction of ethylene oligomerization in the presence of various organoaluminum compounds has been studied. Methylaluminoxane facilitates the formation of alpha-olefins (butene-1, hexene-1) and the byproducts hexene isomers; ethylaluminum dichloride (AlC2H5Cl2) increases the selectivity for alkyltoluenes.
Author keywords:
oligomerization; ethylene; organoaluminum compounds; iron formazanates POLYMERIZATION; COMPLEXES
DOI:
10.1134/S0965544113020072
Web of Science ID:
ISI:000316202200010
Соавторы в МНС:
Другие поля
Поле Значение
Month MAR
Publisher MAIK NAUKA/INTERPERIODICA/SPRINGER
Address 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language English
Keywords-Plus POLYMERIZATION; COMPLEXES
Research-Areas Chemistry; Energy \& Fuels; Engineering
Web-of-Science-Categories Chemistry, Organic; Chemistry, Physical; Energy \& Fuels; Engineering, Chemical; Engineering, Petroleum
Author-Email biosphera@usfeu.ru gbelov@cat.icp.ac.ru khailnaz@yandex.ru slepukhin@ios.uran.ru
Funding-Acknowledgement Russian Academy of Sciences under Presidium program {[}3]; Russian Foundation for Basic Research {[}11-03-90724-mob\_st]
Funding-Text This work was supported in part by the Russian Academy of Sciences under Presidium program no. 3 ``Energy aspects of deep processing of fossil and renewable carbonaceous resources{''} and the Russian Foundation for Basic Research, project no. 11-03-90724-mob\_st.
Number-of-Cited-References 13
Usage-Count-Since-2013 11
Journal-ISO Pet. Chem.
Doc-Delivery-Number 107GD