Catalytic Activity of New Nickel(II) Formazanates in Ethylene Oligomerization / Zaidman A. V.,Khasbiullin I. I.,Belov G. P.,Pervova I. G.,Lipunov I. N. // PETROLEUM CHEMISTRY. - 2012. - V. 52, l. 1. - P. 28-34.

ISSN/EISSN:

0965-5441 / нет данных

Type:

Article

Abstract:

Thirteen mono- and three bisformazans containing one system of azahydrazone bonds have been synthesized, as well as mono- and binuclear complexes on their basis. The kinetic features of ethylene oligomerization in the presence of catalytic systems on the basis of AlEtCl2-activated Ni(II) formazanates differing in composition and structure have been studied. The structures of the mono- and binuclear complexes differ by substituents in the formazan ligand, which have an effect on the activity of the systems and the product composition. The catalytic activity of the binuclear complexes is several times below that of mononuclear Ni(II) formazanates.

Author keywords:

POLYMERIZATION CATALYSTS; OLEFIN POLYMERIZATION; COMPLEXES

DOI:

10.1134/S0965544112010124

Web of Science ID:

ISI:000300729700005

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	JAN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	POLYMERIZATION CATALYSTS; OLEFIN POLYMERIZATION; COMPLEXES
Research-Areas	Chemistry; Energy \& Fuels; Engineering
Web-of-Science-Categories	Chemistry, Organic; Chemistry, Physical; Energy \& Fuels; Engineering, Chemical; Engineering, Petroleum
Author-Email	Zaidman@yandex.ru khailnaz@yandex.ru gbelov@cat.icp.ac.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}10-03-90726-mob\_st]
Funding-Text	This work was supported by the Russian Foundation for Basic Research, project no. 10-03-90726-mob\_st.
Number-of-Cited-References	16
Usage-Count-Since-2013	4
Journal-ISO	Pet. Chem.
Doc-Delivery-Number	898GY