Interactions of titanium carbides, nitrides, and oxides with concentrated mineral acids / Zhilyaev VA,Shveikin GP,Shtin AP // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2001. - V. 46, l. 8. - P. 1133-1136.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

The results on the interaction of TiCx (x = 0.97-0.65), TiNx (x = 0.95-0.61), and TiOx (x = 1.20-0.82) with concentrated hydrochloric, sulfuric, and nitric acids are reported. The discussion is in terms of the electronic structure of metal-like refractory interstitial phases (RIPs) including the details of redox processes accompanying dissolution. The chemical stability of TiCx, TiNx, and TiOx is controlled by the metallicity of Ti-Ti bonds. The factors influencing the stability are the nonmetal of the RIP, the passivating capacity of the nascent reaction products, and gas evolution (or its absence) upon dissolution.

Author keywords:

ELECTRON; TIN

DOI:

нет данных

Web of Science ID:

ISI:000170630400007

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	AUG
Publisher	INTERPERIODICA
Address	PO BOX 1831, BIRMINGHAM, AL 35201-1831 USA
Language	English
Keywords-Plus	ELECTRON; TIN
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Number-of-Cited-References	14
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	466EB