The effects of sulfur and other impurities on carbon-graphite transitions / Tyumentsev VA,Belenkov EA,Shveikin GP,Podkopaev SA // CARBON. - 1998. - V. 36, l. 7-8. - P. 845-853.

ISSN/EISSN:
0008-6223 / нет данных
Type:
Article
Abstract:
The transition to graphite of carbons containing sulfur and the effects of added iron and chromium on this process have been studied using X-ray diffraction analysis and electron microscopy. It was found that after heat treatment in the temperature interval 1300-1600 degrees C carbons containing at least 1.5 mass\% of sulfur, or 0.3 mass\% of sulfur and 1.5 mass\% of added Cr2O3 become heterogeneous; they consist of an ultradisperse matrix and of large (> 100 nm) and sufficiently perfect (Delta d/d(002) similar to 0.002) regions of coherent scattering with interlayer spacing d(002) that corresponds to the graphite-crystal structure. When disperse iron is added, the amount of the graphite phase in this temperature interval decreases by a factor of 2. (C) 1998 Elsevier Science Ltd. All rights reserved.
Author keywords:
petroleum coke; graphitization; X-ray diffraction; phase transactions
DOI:
10.1016/S0008-6223(97)00143-7
Web of Science ID:
ISI:000074773400002
Соавторы в МНС:
Другие поля
Поле Значение
Publisher PERGAMON-ELSEVIER SCIENCE LTD
Address THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language English
Research-Areas Chemistry; Materials Science
Web-of-Science-Categories Chemistry, Physical; Materials Science, Multidisciplinary
ResearcherID-Numbers Vasilii, Tyumentsev/P-5320-2015 Tyumentsev, Vasiliy/O-1990-2013 Belenkov, Evgeny/P-3369-2015
ORCID-Numbers Belenkov, Evgeny/0000-0002-9449-6275
Number-of-Cited-References 18
Usage-Count-Last-180-days 1
Usage-Count-Since-2013 6
Journal-ISO Carbon
Doc-Delivery-Number ZZ846