The effect of degeneration in the thermodynamics of binary salt mixtures / Tkachev NC,Fishman AY,Shunyaev KY // . - 1999. - V. , l. . - P. 596-604.

ISSN/EISSN:

нет данных / нет данных

Type:

Proceedings Paper

Abstract:

A model of ionic mixture, which takes into account the possibility of some ions degenerate states, is proposed. Degeneration removal in such ions is related to random fields, which are caused by topological disorder of ionic melts. Both the boundaries of phase instabilities with respect to the miscibility and the thermodynamics of homogeneous liquid mixture turned out to be very sensitive to the concentration dependence of the random fields dispersion. The results of our estimations for the miscibility gap (where possible) and the thermodynamics of mixing for two classes of mixtures with the degenerate sort of ions in one and in both components are presented and discussed.

Author keywords:

degeneration effects; thermodynamics of mixing; miscibility; spinodal; critical temperature

DOI:

нет данных

Web of Science ID:

ISI:000084132700054

Соавторы в МНС:

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Другие поля

Поле	Значение
Editor	GauneEscard, M
Booktitle	ADVANCES IN MOLTEN SALTS: FROM STRUCTURAL ASPECT TO WASTE PROCESSING
Note	European Research Conference on Molten Salts, PORQUEROLLES ISL, FRANCE, JUN 27-JUL 03, 1998
Organization	European Sci Fdn; USA, European Off; US Aerosp; USN; CNRS; Univ Provence Marseille; French Embassy Moscow; French Embassy Washington; IUSTI; CODATA; MOLTECH
Publisher	BEGELL HOUSE, INC
Address	145 MADISON AVE, NEW YORK, NY 10016 USA
Language	English
ISBN	1-56700-142-4
Research-Areas	Chemistry; Electrochemistry; Physics
Web-of-Science-Categories	Chemistry, Applied; Chemistry, Physical; Electrochemistry; Physics, Atomic, Molecular \& Chemical; Physics, Condensed Matter
ResearcherID-Numbers	Shunyaev, Konstantin/A-3916-2014
Number-of-Cited-References	4
Doc-Delivery-Number	BP10P