Preparation of active aluminum hydroxide and its use for production of finely dispersed alumina / Loginova I.V., Shoppert A.A. // Russian Journal of Non-Ferrous Metals. - 2014. - V. 55, l. 3. - P. 234-237.

ISSN:
10678212
Type:
Article
Abstract:
The preparation of active aluminum hydroxide from the alkali-aluminate solution of the Bayer process with the help of aluminum salt is investigated. For this purpose the ability of the nonuniform crystal growth at low temperatures and without stirring was used. Finally, a precipitate with a high specific surface, which is easily soluble in acids and alkalis, is formed. The activation energy of obtaining active aluminum hydroxide is determined experimentally. This energy constituted 155.4 kJ/mol, which points to the kinetic process mode despite the absence of stirring. The possibility of applying active aluminum hydroxide as a seed for the production of well-crystallized finely dispersed aluminum hydroxide powder, which can be used to fabricate aluminum oxide for nonmetallurgical applications is shown. © 2014 Allerton Press, Inc.
Author keywords:
active aluminum hydroxide; alumina; aluminate solution; aluminum sulfate; precipitation
Index keywords:
Activation energy; Aluminum; Precipitation (chemical); Aluminate solution; Aluminum oxides; Aluminum salts; Aluminum sulfates; High-specific surfaces; Kinetic process; Low temperatures; Non-uniform cr
DOI:
10.3103/S1067821214030080
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84903832739&doi=10.3103%2fS1067821214030080&partnerID=40&md5=ab4c0a93a5f872325412f2c49fb4fc2f
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Affiliations Ural Federal University, ul. Mira 19, Yekaterinburg, 620002, Russian Federation
Author Keywords active aluminum hydroxide; alumina; aluminate solution; aluminum sulfate; precipitation
References Mazalov, Y.A., Fedotov, A.V., Bersh, A.V., (2008) Tekhnol. Metall., p. 8; Tuzhilin, A.S., Lainer, Y.A., Surova, L.M., (2007) Russ. J. Non-Ferrous Met., 48 (2), pp. 98-106; Lainer, Y.A., Surova, L.M., Gashkov, G.I., Vol'fson, G.I., (2000), RF Patent 2175951; Aptikasheva, A.G., Formation of a Porous Structure of Aluminum Hydroxides in Conditions of Sulfate-Aluminate Deposition Method (2006) Extended Abstract of Cand. Sci. (Eng.) Dissertation, , Kazan: Kazan Gos. Univ; Pajot, L., Seigneurin, L., (1981), US Patent 4292295; Brichkin, V.N., Vasil'ev, V.V., Besedin, A.A., Gordyushenkov, E.E., (2011) Sbornik Dokladov 3-Go Mezhdunarodnogo Kongressa "Tsvetnye Metally-2011 (Collected Reports of the 3rd Int. Congr. "Nonferrous Metals-2011), p. 142; Kuznetsov, S.I., Derevyankin, V.A., (1964) Fizicheskaya Khimiya Proizvodstva Glinozema Po Sposobu Baiera (Physical Chemistry of Alumina Production by the Bayer Method), , Moscow: Metallurgiya; Loginova, I.V., Loginov, Y.N., Shoppert, A.A., (2012), RF Patent 2447023; Vol'dman, G.M., Zelikman, A.N., (2003) Teoriya Gidrometallurgicheskikh Protsessov (Theory of Hydrometallurgical Processes), , Moscow: Metallurgiya; Lee, S.O., Jung, K.H., Oa, C.J., (2009) Hydrometallurgy, 98, p. 156
Correspondence Address Loginova, I. V.; Ural Federal University, ul. Mira 19, Yekaterinburg, 620002, Russian Federation; email: loginova_irina@mail.ru
Publisher Allerton Press Incorporation
Language of Original Document English
Abbreviated Source Title Russ. J. Non-ferrous Met.
Source Scopus