Domain structures and local switching in lead-free piezoceramics Ba0.85Ca0.15Ti0.90Zr0.10O3 / Turygin A.P., Neradovskiy M.M., Naumova N.A., Zayats D.V., Coondoo I., Kholkin A.L., Shur V.Y. // Journal of Applied Physics. - 2015. - V. 118, l. 7.

ISSN:
00218979
Type:
Article
Abstract:
Lead-free piezoelectrics are becoming increasingly important in view of environmental problems of currently used lead-based perovskites such as lead zirconate titanate (PZT). One of the recent candidates for PZT replacement, solid solutions of BaZr0.2Ti0.8O3 and Ba0.7Ca0.3TiO3, are investigated in this work by piezoresponse force microscopy. Coexistence of the tetragonal and rhombohedral phases in this material is observed, which probably gives rise to easy polarization switching due to multiple domain states. The period of observed domain lamella scales with the grain size obeying well-known square root dependence characteristic of BaTiO3 ceramics. Domain switching and relaxation are investigated at the nanoscale as a function of the applied voltage and duration of the applied voltage pulses. The observed distortion of piezoresponse hysteresis loops near grain boundaries is attested to the increased concentration of defects. Nanoscale piezoelectric properties of these materials are discussed. © 2015 AIP Publishing LLC.
Author keywords:
Index keywords:
Ferroelectric ceramics; Grain boundaries; Materials properties; Nanotechnology; Piezoelectric ceramics; Scanning probe microscopy; Semiconducting lead compounds; Environmental problems; Lead free piez
DOI:
10.1063/1.4927802
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84939832190&doi=10.1063%2f1.4927802&partnerID=40&md5=e02d02f8728a9ab630430d55bc596bb2
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Art. No. 072002
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Affiliations Institute of Natural Sciences, Ural Federal University, Ekaterinburg, Russian Federation; Department of Physics and CICECO-Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal
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Correspondence Address Turygin, A.P.; Institute of Natural Sciences, Ural Federal UniversityRussian Federation
Publisher American Institute of Physics Inc.
CODEN JAPIA
Language of Original Document English
Abbreviated Source Title J Appl Phys
Source Scopus