Mass and Charge Transfer in Systems Containing Nanocluster Molybdenum Polyoxometallates with a Fullerene Structure / Ostroushko A. A.,Tonkushina M. O.,Martynova N. A. // RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A. - 2010. - V. 84, l. 6. - P. 1022-1027.

ISSN/EISSN:

0036-0244 / нет данных

Type:

Article

Abstract:

The sorption capacity of polyoxometallates with a buckyball structure (fullerene) (NH(4))(42){[}Mo(72)(IV)Mo(60)(V)O(372)(H(3)CCOO)(30)(H(2)O)(72)] center dot 30H(3)CCOONH(4) center dot 250H(2)O and (NH(4))(42){[}Mo(72)(IV)Mo(60)(V)O(372)(ClCH(2)CCOO)(30)(H(2)O)(72)] center dot 250H(2)O center dot 15ClCH(2)COONa with respect to organic substances and nitrogen was studied. The alcohol molecules were found to have at least two types of bond with the sorbent. Some of the molecules evaporate in air, while the rest are held more tightly. It was suggested that the adsorption involved both the outer and inner spheres of buckyballs and that the chemical interaction of the sorbate and sorbent contributed significantly to the process. It was established that the sorption largely depended on the nature of the stabilizing ligands of buckyballs. The parameters of the electrical transfer of the buckyball anions in water solutions were measured; the electric mobility, the transfer number, and the diffusion coefficient were determined.

Author keywords:

INTERFACE; BEHAVIOR; MO132

DOI:

10.1134/S0036024410060233

Web of Science ID:

ISI:000278135600023

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	INTERFACE; BEHAVIOR; MO132
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Physical
Author-Email	alexandre.ostroushko@usu.ru
ResearcherID-Numbers	Tonkushina, Margarita/D-8463-2012
ORCID-Numbers	Tonkushina, Margarita/0000-0003-4371-3900
Funding-Acknowledgement	Russian Foundation for Basic Research {[}07-03-00362]; Federal Education Agency; Federal Agency for Science and Innovation
Funding-Text	This work was financially supported by the Russian Foundation for Basic Research, project no. 07-03-00362; Federal Education Agency and Federal Agency for Science and Innovation.
Number-of-Cited-References	14
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	5
Journal-ISO	Russ. J. Phys. Chem. A
Doc-Delivery-Number	602JO