Thermodynamic properties of uranium in liquid gallium, indium and their alloys / Volkovich V. A.,Maltsev D. S.,Yamshchikov L. F.,Osipenko A. G. // JOURNAL OF NUCLEAR MATERIALS. - 2015. - V. 464, l. . - P. 263-269.

ISSN/EISSN:
0022-3115 / 1873-4820
Type:
Article
Abstract:
Activity, activity coefficients and solubility of uranium was determined in gallium, indium and galliumindium alloys containing 21.8 (eutectic), 40 and 70 wt.\% In. Activity was measured at 573-1073 K employing the electromotive force method, and solubility between room temperature (or the alloy melting point) and 1073 K employing direct physical measurements. Activity coefficients were obtained from the difference of experimentally determined temperature dependencies of uranium activity and solubility. Intermetallic compounds formed in the respective alloys were characterized using X-ray diffraction. Partial and excess thermodynamic functions of uranium in the studied alloys were calculated. Liquidus lines in U-Ga and U-In phase diagrams from the side rich in gallium or indium are proposed. (C) 2015 Elsevier B.V. All rights reserved.
Author keywords:
U-GA; SYSTEM
DOI:
10.1016/j.jnucmat.2015.04.054
Web of Science ID:
ISI:000359170700035
Соавторы в МНС:
Другие поля
Поле Значение
Month SEP
Publisher ELSEVIER SCIENCE BV
Address PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Language English
EISSN 1873-4820
Keywords-Plus U-GA; SYSTEM
Research-Areas Materials Science; Nuclear Science \& Technology
Web-of-Science-Categories Materials Science, Multidisciplinary; Nuclear Science \& Technology
Author-Email v.a.volkovich@urfu.ru
ResearcherID-Numbers Maltsev, Dmitry/C-7431-2015 Volkovich, Vladimir/K-8339-2012
ORCID-Numbers Maltsev, Dmitry/0000-0001-5678-1465 Volkovich, Vladimir/0000-0003-4438-1194
Funding-Acknowledgement Ministry of Education and Science (Russia) {[}N976.42G.04114]; Russian Foundation for Basic Research {[}14-03-31329]
Funding-Text The authors thank Dr. A.V. Chukin and Dr. A.K. Schtoltz for their help with X-ray diffraction measurements and DSM thanks Ministry of Education and Science (Russia), Project No. N976.42G.04114, and Russian Foundation for Basic Research, Contract No. 14-03-31329, for the financial support.
Number-of-Cited-References 15
Usage-Count-Last-180-days 1
Usage-Count-Since-2013 17
Journal-ISO J. Nucl. Mater.
Doc-Delivery-Number CO4ZZ