Influence of heat treatment on the transparency of silicate thin films in the near-IR range / Shardakov N.T., Byzov I.V., Pankratov A.A., Kochedykov V.A. // Glass Physics and Chemistry. - 2008. - V. 34, l. 3. - P. 300-304.

ISSN:
10876596
Type:
Article
Abstract:
The influence of heat treatment on the transmission of silicate thin films prepared by gelation from aqueous solutions of sodium silicate (water glass) is investigated. It is demonstrated that the initial films are characterized by a strong absorption in the IR range due to the presence of hydroxyl groups. The heat treatment of the films at temperatures in the range 150-250°C leads to the step-by-step removal of water from the films and, as a consequence, to an almost complete transmission in the high-frequency IR spectral range. An increase in the heat treatment temperature to 580°C is accompanied by the loss of transparency, most likely, as a result of the pore formation in the film. © 2008 MAIK Nauka.
Author keywords:
Index keywords:
Absorption; Alkali metals; Coagulation; Coatings; Colloids; Gelation; Heat treating furnaces; Heat treatment; Iridium; Metal analysis; Optical properties; Optics; Silicates; Silicon compounds; Sodium;
DOI:
10.1134/S1087659608030103
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-45749110211&doi=10.1134%2fS1087659608030103&partnerID=40&md5=c64c34a36acb5e143a993bb357892e16
Соавторы в МНС:
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Affiliations Russian State Vocational Pedagogical University, ul. Mashinostroitelei 11, Yekaterinburg, 620012, Russian Federation; Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Yekaterinburg, 620219, Russian Federation
References Appen, A.A., (1967) Vysokotemperatunye Neorganicheskie Pokrytiya, , Khimiya Leningrad (Heat-Resistant Inorganic Coatings); Petzold, A., Pöschman, G., (1986) Email und Emailliertechnik, , Leipzig, Grundstoffidustrie; (1990) Emal' i Emalirovanie, , Moscow: Metallurgiya [in German and in Russian]; Borisenko, A.I., Nikolaeva, L.V., (1980) Tonkosloinye Stekloemalevye i Steklokeramicheskie Pokrytiya, , Nauka Leningrad (Thin-Layer Glass-Enamel and Glass-Ceramic Coatings); Krasovskii, A.N., Odlyanitsaya, V.S., Baranov, V.G., Agafonov, G.I., Infrared spectra and the structure of thin layers in alkali metal silicates (1989) Lakokras. Mater., (6), pp. 81-85; Matveev, M.A., Guzhavina, E.T., On the Structural and Mineral-Phase Transformations upon Solidification of Aqueous Solutions of Alkali Silicates (1967) Neorg. Mater., 3, pp. 695-699. , 4; Yukhnevich, G.V., (1973) Infrakrasnaya Spektroskopiya Vody, , Nauka Moscow (Infrared Spectroscopy of Water); Lygin, V.I., Models of "hard" and "soft" Surfaces: The Design of the Microstructure of the Surface of Silicas (2002) Ross. Khim. Zh., 46, pp. 12-18. , 3; Lazarev, A.N., (1968) Kolebatel'Nye Spektry i Stroenie Silikatov, , Nauka Leningrad (Vibrational Spectra and the Structure of Silicates); Lebedeva, S.M., Vishnevskii, S.A., Bykov, V.N., Composition and structure of impact glasses (2004) Elektron. Nauchn.-Inf. Zh., (1-22), pp. 1-2; Taylor, W.R., Application of Infrared Spectroscopy to Studies of Silicate Glass Structure: Examples from the Melilite Glasses and the Systems Na 2O-SiO2 and Na2O-Al2O 3-SiO2 (1990) Proc.-Indian Acad. Sci., Earth and Planet. Sci., 99, pp. 99-117; Poe, B.T., McMillan, P.F., Angell, C.A., Sato, R.K., Al and Si Coordination in SiO2-Al2O3 Glasses and Liquids: A Study by NMR and IR Spectroscopy and MD Simulations (1992) Chem. Geol., 96, pp. 333-349; Toporets, A.S., (1988) Optika Sherokhovatykh Poverkhnostei, , Mashinostroenie Leningrad (Optics of Rough Surfaces); Kukolev, G.V., (1966) Khimiya Kremniya i Fizicheskaya Khimiya Silikatov, , Vysshaya Shkola Moscow (Chemistry of Silicon and the Physical Chemistry of Silicates)
Correspondence Address Shardakov, N. T.; Russian State Vocational Pedagogical University, ul. Mashinostroitelei 11, Yekaterinburg, 620012, Russian Federation; email: shardan@sky.ru
Language of Original Document English
Abbreviated Source Title Glass Phys. Chem.
Source Scopus