Transformation of 1,2,3-Thiadiazolyl Hydrazones as Method for Preparation of 1,2,3-Triazolo[5,1-b][1,3,4]thiadiazines / Kalinina T.A., Bystrykh O.A., Glukhareva T.V., Morzherin Y.Y. // Journal of Heterocyclic Chemistry. - 2017. - V. 54, l. 1. - P. 137-146.

ISSN:
0022152X
Type:
Article
Abstract:
The transformation of 1,2,3-thiadiazolyl hydrazones of aldehydes and ketones including Dimroth rearrangement giving 1-alkylidenamino-5-mercapto-1,2,3-triazoles, alkylation of mercapto group of these heterocyclic compounds by α-bromoacetophenones and cyclization giving 6,7-dihydro-5H-[1,2,3]triazolo[5,1-b][1,3,4]thiadizines have been investigated. It was shown that the reaction for hydrazones of acetophenones and benzoaldehydes is diastereoselective. Triazolothiadiazine spiro derivatives were prepared with transformation of hydrazones of cyclic ketones. © 2015 HeteroCorporation
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DOI:
10.1002/jhet.2554
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Affiliations Department of Organic Chemical Technology, Ural Federal University Named After the First President of Russia B. N. Yeltsin, 19 Mira str., Ekaterinburg, Russian Federation
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Correspondence Address Kalinina, T.A.; Department of Organic Chemical Technology, Ural Federal University Named After the First President of Russia B. N. Yeltsin, 19 Mira str., Russian Federation; email: tasika06@mail.ru
Publisher HeteroCorporation
CODEN JHTCA
Language of Original Document English
Abbreviated Source Title J. Heterocycl. Chem.
Source Scopus