Role of polar solvents for the synthesis of pillar{[}6]arenes / Santra S.,Kovalev I. S.,Kopchuk D. S.,Zyryanov G. V.,Majee A.,Charushin V. N.,Chupakhin O. N. // RSC ADVANCES. - 2015. - V. 5, l. 126. - P. 104278-104282.

ISSN/EISSN:

2046-2069 / нет данных

Type:

Article

Abstract:

An efficient procedure for the synthesis of pillar{[}6]arenes has been developed. The procedure involves the condensation of 1,4-dialkoxybenzenes and paraformaldehyde in the presence of a catalytic amount of H2SO4 or BF3 center dot OEt2 in polar solvent media (acetonitrile, ethyl alcohol, acetone etc.). In all cases the interaction afforded pillar{[}6]arenes in high yields.

Author keywords:

HOST-GUEST COMPLEXATION; HIGH-YIELD SYNTHESIS; WATER CHANNELS; DRIVEN; RECOGNITION; MOLECULES; FACILE; PILLARARENES; CAVITIES; BINDING

DOI:

10.1039/c5ra19569a

Web of Science ID:

ISI:000366433700063

Соавторы в МНС:

Другие поля

Поле	Значение
Publisher	ROYAL SOC CHEMISTRY
Address	THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Language	English
Keywords-Plus	HOST-GUEST COMPLEXATION; HIGH-YIELD SYNTHESIS; WATER CHANNELS; DRIVEN; RECOGNITION; MOLECULES; FACILE; PILLARARENES; CAVITIES; BINDING
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	gvzyryanov@gmail.com adinath.majee@visva-bharati.ac.in chupakhin@ios.uran.ru
Funding-Acknowledgement	Russian Science Foundation {[}15-13-10033]; BRNS-DAE {[}37(2)/14/35/2014-BRNS/563]
Funding-Text	This work was supported by the Russian Science Foundation (Ref. \# 15-13-10033) and, for A. M, by BRNS-DAE (Ref. No. 37(2)/14/35/2014-BRNS/563, June 10, 2014).
Number-of-Cited-References	55
Usage-Count-Last-180-days	6
Usage-Count-Since-2013	19
Journal-ISO	RSC Adv.
Doc-Delivery-Number	CY5FO