Synthesis of photochromic 6-aryl-substituted bis(benzothiophenyl)perfluorocyclopentenes by the Suzuki-Miyaura cross-coupling / Krayushkin Mikhail M.,Bogacheva Anna M.,Levchenko Konstantin S.,Kobeleva Olga I.,Valova Tatyana M.,Barachevskii Valery A.,Pozzo Jean-Luc,Struchkova Marina I.,Shmelin Pavel S.,Kalik Marina A.,Baryshnikova Tatiana K.,Charushin Valery N. // MENDELEEV COMMUNICATIONS. - 2013. - V. 23, l. 2. - P. 78-80.

ISSN/EISSN:
0959-9436 / нет данных
Type:
Article
Abstract:
The Suzuki cross-coupling of 1,2-bis(6-iodo-2-methylbenzo{[}b]thiophen-3-yl)hexafluorocyclopentene and (het)arylboronic acids depending on the reaction conditions affords bis- or mono-adducts. The latter on next cross-coupling with different boronic acid give unsymmetrical dihetarylethenes. Spectral-kinetic studies of the photoinduced cyclization of the compounds obtained were performed.
Author keywords:
REFRACTIVE-INDEX CHANGE; CLOSED-RING FORM; MAGNETIC INTERACTION; HIGHLY FLUORESCENT; DIARYLETHENE; DERIVATIVES; PERFLUOROCYCLOPENTENE; BEARING; SYSTEMS; POLYMER
DOI:
10.1016/j.mencom.2013.03.007
Web of Science ID:
ISI:000317452500007
Соавторы в МНС:
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Другие поля
Поле Значение
Month MAR-APR
Publisher ELSEVIER SCIENCE BV
Address PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Language English
Keywords-Plus REFRACTIVE-INDEX CHANGE; CLOSED-RING FORM; MAGNETIC INTERACTION; HIGHLY FLUORESCENT; DIARYLETHENE; DERIVATIVES; PERFLUOROCYCLOPENTENE; BEARING; SYSTEMS; POLYMER
Research-Areas Chemistry
Web-of-Science-Categories Chemistry, Multidisciplinary
Author-Email mkray@ioc.ac.ru anna-bogacheva86@yandex.ru
ORCID-Numbers Bogacheva, Anna/0000-0002-3061-6979
Funding-Acknowledgement Russian Foundation for Basic Research {[}11-03-90736]
Funding-Text This work was supported by the Russian Foundation for Basic Research (grant no. 11-03-90736). The authors are grateful to Dr. A. Yu. Bochkov for helpful suggestions.
Number-of-Cited-References 27
Usage-Count-Last-180-days 3
Usage-Count-Since-2013 23
Journal-ISO Mendeleev Commun.
Doc-Delivery-Number 124GT