Unusual magnetic behavior of the new supramolecular ensemble {[}Ni2L4](2)center dot{[}NiCl2(LH)(2)(MeCN)(2)]center dot 4MeCN (LH is 2-mercaptobenzimidazole) / Nikiforova M. E.,Talismanova M. O.,Aleksandrov G. G.,Kotovskaya S. K.,Sidorov A. A.,Novotortsev V. M.,Ikorskii V. N.,Charushin V. N.,Eremenko I. L.,Moiseev I. I. // RUSSIAN CHEMICAL BULLETIN. - 2006. - V. 55, l. 12. - P. 2181-2186.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The diamagnetic dinuclear complex Ni2L4 was synthesized by the reaction of NiCl2 center dot 6H(2)O with 2-mercaptobenzimidazole (LH) in ethanol in the presence of Et3N. The solid-state reaction (reagent ratio Ni: LH = 1: 2) followed by recrystallization of the reaction product from a MeCN-THF mixture afforded crystals of the associate {[}Ni2L4](2)center dot{[}NiCl2(LH)(2)(MeCN)(2)] containing four acetonitrile solvate molecules. Crystals of 2 center dot 4MeCN exhibit ferromagnetic properties at helium temperatures.

Author keywords:

mono-and dinuclear 2-mercaptobenzimidazole nickel(II) complexes; X-ray diffraction study; magnetic properties MOLECULAR-STRUCTURES; NI-II; COMPLEXES; LIGANDS; ATOMS

DOI:

10.1007/s11172-006-0570-y

Web of Science ID:

ISI:000247390900008

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	DEC
Publisher	SPRINGER
Address	233 SPRING STREET, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	MOLECULAR-STRUCTURES; NI-II; COMPLEXES; LIGANDS; ATOMS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	ikorsk@tomo.nsc.ru charushin@ios.uran.ru ilerem@igic.ras.ru
ResearcherID-Numbers	Sidorov, Alexey/C-1652-2013 Eremenko, Igor/N-7242-2015 Novotortsev, Vladimir/C-3934-2013
ORCID-Numbers	Eremenko, Igor/0000-0001-6861-1404
Number-of-Cited-References	16
Usage-Count-Since-2013	5
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	180UF