Ni(II)-Mediated nitrosation of oximes bearing an alpha-CH2 group / Makarycheva-Mikhailova Anastassiya V.,Gushchin Pavel V.,Kopylovich Maximilian N.,Ganebnykh Ilya N.,Charushin Valery N.,Haukka Matti,Pombeiro Armando J. L.,Kukushkin Vadim Yu. // INORGANIC CHEMISTRY COMMUNICATIONS. - 2006. - V. 9, l. 8. - P. 869-871.

ISSN/EISSN:

1387-7003 / нет данных

Type:

Article

Abstract:

Heating of NiCl2 center dot 6H(2)O with 10-fold excess of an oxime having an alpha-CH2 group (1-4) at 100 degrees C for I day in air leads to the formation of the dioxime/ato complexes {[}Ni(dioxime/ato)(2)] (5-8) formed due to a novel type of metal-mediated nitrosation. Compounds 5-8 were characterized by elemental analyses, FAB (5-7) or APCI (8) mass-spectrometry, IR, H-1 and C-13\{H-1\} spectroscopies (for 8), and X-ray structural study has been performed for 5 and 8; the corresponding ketones (9-12) were identified by LC-MS. (C) 2006 Elsevier B.V. All rights reserved.

Author keywords:

nickel(II); oximes; dioximes; metal-mediated reaction; nitrosation MEDIATED DEHYDRATION; CRYSTAL-STRUCTURE; METAL-COMPLEXES; REACTIVITY; CHLORINATION; SALICYLALDOXIME; ORGANONITRILES; PLATINUM; EXAMPLE; ACETONE

DOI:

10.1016/j.inoche.2006.04.008

Web of Science ID:

ISI:000239476400026

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	AUG
Publisher	ELSEVIER SCIENCE BV
Address	PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Language	English
Keywords-Plus	MEDIATED DEHYDRATION; CRYSTAL-STRUCTURE; METAL-COMPLEXES; REACTIVITY; CHLORINATION; SALICYLALDOXIME; ORGANONITRILES; PLATINUM; EXAMPLE; ACETONE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Author-Email	pombeiro@ist.utl.pt kukushkin@VK2100.spb.edu
ResearcherID-Numbers	Kopylovich, Maximilian/H-8625-2012 Kukushkin, Vadim/H-1629-2013 Pombeiro, Armando/I-5945-2012 Gushchin, Pavel/H-5047-2013
ORCID-Numbers	Kopylovich, Maximilian/0000-0002-6307-327X Kukushkin, Vadim/0000-0002-2253-085X Pombeiro, Armando/0000-0001-8323-888X Gushchin, Pavel/0000-0001-8847-219X
Number-of-Cited-References	27
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	8
Journal-ISO	Inorg. Chem. Commun.
Doc-Delivery-Number	069VI