ON THE ELECTROCHEMICAL TRANSFORMATION OF ADSORBATES, AND THE NATURE OF THE DISORDER OF SOLIDS / BRAININA KZ,KHODOS MY,BELISHEVA GM,VIDREVICH MB // ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE. - 1990. - V. 168, l. 1. - P. 65-91.

ISSN/EISSN:

0044-3336 / нет данных

Type:

Article

Abstract:

A relationship has been established between electrochemical transformations (redox processes) of sorption species (oxygen and hydrogen) on the surface of oxidic compounds (especially vanadates of alkaline earth metals), and the nature of the crystal disorder, lattice energy and crystallochemical non-equivalence of oxygen in the structure. The magnitude of electrochemical signals is determined by the disorder of the anionic sublattice, which is accompanied by electronic disorder of the crystal, and by the enthalpy of formation and the melting temperature of the compound. The set of signals depends on the number of crystallochemical non-equivalent sites of oxygen.

Author keywords:

OXYGEN CHEMISORPTION; ELECTROCHEMICAL REDUCTION OF OXYGEN; CARBON PASTE ELECTRODE; DISORDER OF SOLIDS; EARTH ALKALI VANADATES SYSTEM

DOI:

нет данных

Web of Science ID:

ISI:A1990EX88000005

Соавторы в МНС:

—

Другие поля

Поле	Значение
Publisher	R OLDENBOURG VERLAG
Address	ROSENHEIMER STR 145 POSTFACH 801360, W-8000 MUNICH 80, GERMANY
Language	English
Keywords-Plus	SYSTEM
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Physical
Number-of-Cited-References	42
Doc-Delivery-Number	EX880