Luminescent neutral lanthanide complexes of 5-aryl-2,2 `-bipyridine-6-carboxylic acids, synthesis and properties / Krinochkin Alexey P.,Kopchuk Dmitry S.,Kozhevnikov Dmitry N. // POLYHEDRON. - 2015. - V. 102, l. . - P. 556-561.

ISSN/EISSN:

0277-5387 / нет данных

Type:

Article

Abstract:

Luminescent lanthanide complexes of 4-aryl-1-(2-pyridyl)-6,7-dihydro-5H-cyclopenta{[}c]pyridine-3-carboxylic acids and 5-toly1-2,2'-bipyridine-6-carboxylic acid were prepared. The ligands were synthesized using the ``1,2,4-triazine{''} methodology. In one case, the opportunity of copper complex preparation, followed by exchange of the metal cation from copper to europium to overcome synthetic difficulties, was demonstrated. The ability of tuning the properties of the complexes by means of varying the structure of the ligands was demonstrated. In particular, the introduction of the cyclopentene moiety allowed the preparation of highly soluble complexes in non-polar organic solvents. (C) 2015 Elsevier Ltd. All rights reserved.

Author keywords:

5-Aryl-2,2 `-bipyridine-6-carboxylic acids; Luminescence; Lanthanide complexes; Aza-Diels-Alder reaction; 1,2,4-Triazine LAVENDAMYCIN PARTIAL STRUCTURES; DIELS-ALDER REACTION; POTENT PHARMACOPHORE; COORDINATED NITRILES; HIGHLY LUMINESCENT; TRIDENTATE LIGANDS; METAL-IONS; 2,2'-BIPYRIDINE; STREPTONIGRIN; 1,2,4-TRIAZINES

DOI:

10.1016/j.poly.2015.09.055

Web of Science ID:

ISI:000367757100071

Соавторы в МНС:

Другие поля

Поле	Значение
Month	DEC 14
Publisher	PERGAMON-ELSEVIER SCIENCE LTD
Address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language	English
Keywords-Plus	LAVENDAMYCIN PARTIAL STRUCTURES; DIELS-ALDER REACTION; POTENT PHARMACOPHORE; COORDINATED NITRILES; HIGHLY LUMINESCENT; TRIDENTATE LIGANDS; METAL-IONS; 2,2'-BIPYRIDINE; STREPTONIGRIN; 1,2,4-TRIAZINES
Research-Areas	Chemistry; Crystallography
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Crystallography
Author-Email	dkopchuk@mail.ru
Funding-Acknowledgement	Russian Scientific Found {[}15-13-10033]
Funding-Text	This work was supported by the Russian Scientific Found (Grant \# 15-13-10033).
Number-of-Cited-References	45
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	16
Journal-ISO	Polyhedron
Doc-Delivery-Number	DA4GC