Influence of the ligand nature on the boundary conditions of the formation and the morphology of nanocrystalline cadmium sulfide films / Forostyanaya N. A.,Maskaeva L. N.,Markov V. F. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2015. - V. 85, l. 11. - P. 2513-2519.

ISSN/EISSN:

1070-3632 / 1608-3350

Type:

Article

Abstract:

Ionic equilibriums in the Cd2+-L-N2H4CS (L = NH3, H2NCH2CH2NH2, C6H5O (7) (3-) , NH3 + C6H5O (7) (3-) ) systems have been analyzed. The ranges and boundary conditions of the formation of cadmium sulfide CdS and the accompanying Dd(OH)(2) and DdCN(2) impurity phases have been determined. 100-200 nm thick nanocrystalline cadmium sulfide films constituted by 10-30-nm particles arranged into globules with diameter of 400-700 nm have been synthesized. The effects of the nature and strength of the complexing agent on the microstructure and morphology of the resultant CdS layers have been demonstrated using scanning electron microscopy.

Author keywords:

hydrochemical synthesis; ionic equilibrium; thin film; cadmium sulfide; surface morphology CHEMICAL BATH DEPOSITION; CDS

DOI:

10.1134/S1070363215110031

Web of Science ID:

ISI:000367345700003

Соавторы в МНС:

Другие поля

Поле	Значение
Month	NOV
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3350
Keywords-Plus	CHEMICAL BATH DEPOSITION; CDS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	natal-ku8@yandex.ru
Funding-Acknowledgement	Ministry of Education and Science of the Russian Federation {[}4.1270.2014/K]; Government of the Russian Federation {[}211, 02.A03.21.0006]; Ural Federal University
Funding-Text	This work was financially supported by the Ministry of Education and Science of the Russian Federation in the framework of the governmental task (no. 4.1270.2014/K), the Government of the Russian Federation in the framework of Program no. 211 (project no. 02.A03.21.0006), and the Ural Federal University in the framework of the Development Program for the ``Young Scientists of the Ural Federal University{''} contest winners.
Number-of-Cited-References	18
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	CZ8JJ