Mass spectrometric study of the bromination of technical mixtures of polychlorinated biphenyls / Pervova M. G.,Plotnikova K. A.,Mekhaev A. V.,Pestov A. V.,Saloutin V. I.,Chupakhin O. N. // DOKLADY CHEMISTRY. - 2016. - V. 466, l. 2. - P. 29-34.

ISSN/EISSN:

0012-5008 / 1608-3113

Type:

Article

Abstract:

The products of bromination of polychlorinated biphenyls (PCBs) that constitute Trichlorobiphenyl and Sovol PCB technical mixtures were studied by gas chromatography-mass spectrometry. On the basis of mass spectrometric data, the reaction was shown to result in formation of a mixture of poly(bromochloro)biphenyls containing from one to five bromine atoms and from two to six chlorine atoms in different combinations. It was found that the content of monobromo derivatives increases while the content of di-, tri-, and tetrabromo PCB derivatives decreases when the chlorination degree of the initial PCBs increases.

Author keywords:

нет данных

DOI:

10.1134/S0012500816010067

Web of Science ID:

ISI:000374102600003

Соавторы в МНС:

Другие поля

Поле	Значение
Month	FEB
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3113
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	pervova@ios.uran.ru
Funding-Acknowledgement	Ural Branch, Russian Academy of Sciences (Consolidated Research Program)
Funding-Text	This work was supported by the Ural Branch, Russian Academy of Sciences (Consolidated Research Program).
Number-of-Cited-References	9
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	1
Journal-ISO	Dokl. Chem.
Doc-Delivery-Number	DJ3KA