Effect of vanadium doping on the magnetic properties of LiMnPO4 / Kellerman D.G., Chukalkin Y.G., Medvedeva N.I., Gorshkov V.S., Semenova A.S. // Physica Status Solidi (B) Basic Research. - 2016. - V. 253, l. 5. - P. 965-975.

ISSN:

03701972

Type:

Article

Abstract:

Vanadium-substituted LiMnPO4 has been synthesized by the solid state reaction route. To obtain tetravalent state of vanadium, the samples have been additionally annealed under hydrogen atmosphere. Comparative magnetic and neutron powder diffraction investigations of the two solid-solution lines were performed as a function of V content. The divergence between static zero-field-cooled (ZFC) and field-cooled (FC) magnetizations in the fields of H<1 T and the magnetization hysteresis indicating the presence of a ferromagnetic component were observed for all vanadium concentrations. The ferromagnetic component in the reduced V-doped LiMnPO4 is more intensive than in the as-prepared samples. To gain insight into the reason for this effect, the formation energies of antisite defects in V-doped and reduced LiMnPO4 were calculated within the density functional theory. The appearance of the ferromagnetic clusters above the Néel temperature is discussed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Author keywords:

Annealing; Antisite defects; Doping; Exchange interactions; LiMnPO4; Magnetic susceptibility; Vanadium

Index keywords:

нет данных

DOI:

10.1002/pssb.201552682

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84964706603&doi=10.1002%2fpssb.201552682&partnerID=40&md5=952a409b7f06a5571a04a36efc09f2c3

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84964706603&doi=10.1002%2fpssb.201552682&partnerID=40&md5=952a409b7f06a5571a04a36efc09f2c3
Affiliations	Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, 91, Pervomaiskaya St., Ekaterinburg, Russian Federation; Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Russian Federation; Eliont JSC, Ekaterinburg, Russian Federation
Author Keywords	Annealing; Antisite defects; Doping; Exchange interactions; LiMnPO4; Magnetic susceptibility; Vanadium
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Correspondence Address	Kellerman, D.G.; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, 91, Pervomaiskaya St., Russian Federation; email: kellerman@ihim.uran.ru
Publisher	Wiley-VCH Verlag
Language of Original Document	English
Abbreviated Source Title	Phys. Status Solidi B Basic Res.
Source	Scopus