EPR of hole centers in nonlinear LiBO3 crystals / Porotnikov AV,Ogorodnikov IN,Kudyakov SV,Kruzhalov AV,Votyakov SL // PHYSICS OF THE SOLID STATE. - 1997. - V. 39, l. 8. - P. 1224-1227.

ISSN/EISSN:
1063-7834 / 1090-6460
Type:
Article
Abstract:
Results are presented of an EPR study of theO(-) hole center in LiB3O5 (lithium triborate) crystals. Analysis of angular dependences of EPR spectra is used to determine the principal values of the g tensor (g(XX) = 2.032, g(YY) = 2.020, g(ZZ) = 2.007), along with the modulus of the isotropic part of the A(2) tensor (\textbackslash{}A\textbackslash{} = 12.2 G) and the orientations of the principal axes of the paramagnetic O- center. The most probable model for the O- center in lithium berate crystals is the following: a hole trapped by the center is localized on ap-orbital of an oxygen ion linking two boron atoms with coordination numbers three and four near a negatively charged stabilizing structural defect. In this case the characteristic hyperfine splitting is due primarily to the interaction of the unpaired electron spin with the B-11 nucleus. (C) 1997 American Institute of Physics.
Author keywords:
OPTICAL CRYSTAL; LIB3O5; LUMINESCENCE
DOI:
10.1134/1.1130048
Web of Science ID:
ISI:A1997XV62400014
Соавторы в МНС:
Другие поля
Поле Значение
Month AUG
Publisher MAIK NAUKA/INTERPERIODICA/SPRINGER
Address 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language English
EISSN 1090-6460
Keywords-Plus OPTICAL CRYSTAL; LIB3O5; LUMINESCENCE
Research-Areas Physics
Web-of-Science-Categories Physics, Condensed Matter
ResearcherID-Numbers Porotnikov, Alexey/A-8016-2012 Ogorodnikov, Igor/B-4162-2011
ORCID-Numbers Ogorodnikov, Igor/0000-0002-4700-2340
Number-of-Cited-References 17
Usage-Count-Since-2013 7
Journal-ISO Phys. Solid State
Doc-Delivery-Number XV624